Virtual Modelling and Electromagnetic Absorption Analysis of ZnO/SiO₂-PCL Composites
DOI:
https://doi.org/10.36602/jsba.2025.20.59%20Keywords:
Microwave Absorbing, Complex permittivity, Absorption coefficient, Reflection loss.Abstract
Recent research has focused on developing electromagnetic wave absorbers that exhibit high absorption performance, thin thickness, low density, light weight, low cost, and a broad absorption bandwidth. In this study, a virtual model of a polycaprolactone (PCL)-based composite reinforced with varying proportions of nano zinc oxide (ZnO) and silicon dioxide (SiO₂) was developed using COMSOL Multiphysics. A rectangular waveguide structure was designed to simulate a Network Analyzer (NWA) setup used for wave transmission measurements. The complex permittivity of the composites was calculated for different ZnO and SiO₂ contents. The results revealed that the dielectric constant increased from 2.893 to 3.833, and the dielectric loss factor rose from 0.253 to 0.369 with higher filler loading. Consequently, the reflection loss (RL) decreased to 3.718 dB, while the absorption coefficient increased to 0.110, and the attenuation coefficient reached 3.2393 dB at 10 GHz for an absorber thickness of 0.003 m. These findings demonstrate the potential of PCL/ZnO/SiO₂ composites as lightweight and efficient microwave absorbing materials.
References
[1] N. Wongkasem, "Electromagnetic pollution alert: Microwave radiation and absorption in human organs and tissues," Electromagnetic Biology and Medicine, vol. 40, no. 2, pp. 236–253, 2021.
[2] K. A. Hossain, "Study on electromagnetic interference (EMI) and electromagnetic compatibility (EMC): Sources and design concept for mitigation of EMI/EMC," Journal of Liberal Arts and Humanities (JLAH), vol. 4, no. 8, pp. 68–96, 2023.
[3] Z. Wei, Z. Li, D. Chen, J. Liang, and J. Kong, "Recent progress of advanced composites for broadband electromagnetic wave absorption," Small Structures, vol. 6, no. 7, p. 2400615, 2025.
[4] L. Yan, J. Wang, X. Han, Y. Ren, Q. Liu, and F. Li, "Enhanced microwave absorption of Fe nanoflakes after coating with SiO2 nanoshell," Nanotechnology, vol. 21, no. 9, Art. no. 095708, 2010.
[5] M. Chen, Y. Zhu, Y. Pan, H. Kou, H. Xu, and J. Guo, "Gradient multilayer structural design of CNTs/SiO2 composites for improving microwave absorbing properties," Materials & Design, vol. 32, no. 5, pp. 3013–3016, 2011.
[6] F. Ahmad, Z. Abbas, S. J. Obaiys, and D. M. Abdalhadi, "Attenuation performance of polymer composites incorporating NZF Filler for electromagnetic interference shielding at microwave frequencies," J. Mater. Sci Eng, vol. 5, p. 2169-0022, 2016.
[7] L. Feng et al., "Two-dimensional transition metal dichalcogenides based composites for microwave absorption applications: a review," J. Phys.: Energy, 2022
[8] Y. I. Abdulkarim et al., “A review on metamaterial absorbers: Microwave to optical,” Frontiers in Physics, vol. 10, p. 893791, 2022.
[9] J. Huo, L. Wang, and H. Yu, "Polymeric nanocomposites for electromagnetic wave absorption," J. Mater. Sci., vol. 44, no. 14, pp. 3917–3927, Jul. 2009.
[10] T. Sajjad, M. Maleki, and M. Babamoradi, “Microwave absorption theory and recent advances in microwave absorbers by polymer-based nanocomposites (carbons, oxides, sulfides, metals, and alloys),” Inorg. Chem. Commun., vol. 153, p. 110407, 2023, doi: 10.1016/j.inoche.2023.110407.
[11] V. J. Hegde, O. Gallot-Lavallée, and L. Heux, “Dielectric study of Polycaprolactone: A biodegradable polymer,” in 2016 IEEE Int. Conf. on Dielectrics (ICD), vol. 1, pp. 293-296,Jul.2016,doi:10.1109/ICD.2016.7547565.
[12] L. W. McKeen, Permeability properties of plastics and elastomers. William Andrew, 2016.
[13] L. Jiang and J. Zhang, “Biodegradable and biobased polymers,” in Applied plastics engineering handbook, W. Andrew Pub., 2017, pp. 127–143.
[14] X. H. Tang, J. Li, Y. J. Tan, J. H. Cai, J. H. Liu, and M. Wang, “Achieve highperformance microwave shielding in poly (ε-caprolactone)/multi-wall carbon nanotube composites via balancing absorption in conductive domains and multiple scattering at interfaces,” Appl. Surf. Sci., vol. 508, p. 145178,2020,doi:10.1016/j.apsusc.2019.145178.
[15] A. Yakubu, Z. Abbas, N. A. Ibrahim, and A. Fahad, “Reduction of electromagnetic interference using ZnO-PCL nanocomposites at microwave frequency,” Adv. Mater. Sci. Eng.,vol.2015,2015,doi:10.1155/2015/141029. .
[16] S.O. Nelson, “Measurement and calculation of powdered mixture permittivities,” IEEE Trans. Instrum. Meas., vol. 50, no. 5, pp. 1066–1070, Oct. 2001, doi: 10.1109/19.963162.
[17] E. E. Mensah, Z. Abbas, N. A. Ibrahim, A. M. Khamis, and D. M. Abdalhadi, “Complex permittivity and power loss characteristics of α-Fe$_2O_3$/polycaprolactone (PCL) nanocomposites: Effect of recycled α-Fe$_2O_3$ nanofiller,” Heliyon, vol. 6, no. 12, p. e05595, Dec. 2020, doi: 10.1016/j.heliyon. 2020.e05595. .
[18] Y. Yang, W. Guo, X. Wang, Z. Wang, J. Qi, and Y. Zhang, “Size dependence of dielectric constant in a single pencil-like ZnO nanowire,” Nano Lett., vol. 12, no. 4, pp. 1919–1922, Apr. 2012, doi: 10.1021/nl204482m.
[19] B. Du, M. Cai, X. Wang, J. Qian, C. He, and A. Shui, “Enhanced electromagnetic wave absorption property of binary ZnO/NiCo$_2O_4$ composites,” J. Adv. Ceram., vol. 10, no. 4, pp. 832–842, Jul. 2021, doi: 10.1007/s40145-021-0466-4.
[20] Q. Chen, L. Li, Z. Wang, Y. Ge, C. Zhou, and J. Yi, “Synthesis and enhanced microwave absorption performance of CIP@SiO2@Mn0.6Zn0.4Fe2O4 ferrite composites,” J. Alloys Compd., vol. 779, pp. 720–727, Mar. 2019, doi: 10.1016/j.jallcom.2018.11.298.
[21] G. Liu, L. Wang, G. Chen, S. Hua, C. Ge, H. Zhang, and R. Wu, “Enhanced electromagnetic absorption properties of carbon nanotubes and zinc oxide whisker microwave absorber,” J. Alloys Compd., vol. 514, pp. 183–188, Feb. 2012, doi: 10.1016/j.jallcom.2011.10.106.
[22] Y. Liu, X. Du, C. Wu, Y. Liu, Y. Liu, and G. Zhao, “Reduced graphene oxide decorated with ZnO microrods for efficient electromagnetic wave absorption performance,” J. Mater. Sci.: Mater. Electron., vol. 31, no. 11, pp. 8637–8648, Jun. 2020, doi: 10.1007/s10854-020-03387-y
[23] A. F. Ahmad, Z. Abbas, S. J. Obaiys, and D. M. Abdalhadi, “Attenuation performance of polymer composites incorporating NZF Filler for electromagnetic interference shielding at microwave frequencies,” J. Mater. Sci. Eng., vol. 5, no. 1, p. 2169-0022, Jan. 2016.
[24] L. Zhang, L. Wang, Q. Wang, and W. Ding, “Dielectric, magnetic, and microwave absorbing properties of Ag-plated terapod-like ZnO whiskers,” Mater. Sci. Eng. B, vol. 262, p. 114682, Dec. 2020, doi: 10.1016/j.mseb.2020.114682.
[25] Z. Jia, J. Liu, and G. Wu, “Molecular Intercalation‐Induced Two‐Phase Evolution Engineering of 1T and 2H-MS2 (M=Mo,V,W) for Interface‐Polarization‐Enhanced Electromagnetic Absorbers,” Adv.








