The Corrosion Inhibition of The Carbon Steel and Oil Pipelines in 1 M H2SO4 by Expired Atarax and Tussinor, Drugs

المؤلفون

  • Hamdy AB. Matter Chemistry Department, Banghazi University, El-Wahat, Jalu, Libya
  • Tariq M. Ayad Chemistry Department, Banghazi University, El-Wahat, Jalu, Libya
  • Abdulrhman A.I. Alkatly Chemistry Department, Banghazi University, El-Wahat, Jalu, Libya

DOI:

https://doi.org/10.36602/jsba.2023.16.93%20

الكلمات المفتاحية:

Corrosion inhibitors، Carbon steel، Oil pipelines، Expired drugs، Potentiometric method

الملخص

Metal corrosion is an industrial and economic problem, especially in the oil industry, where it is transported and stored in carbon steel tanks. In turn, we are looking for inexpensive, economical and effective solutions to increase industrial development and economic growth. We have studied two expired drugs, Atarax. (At.) (Hydroxyzine hydrochloride), and Tussinor (Tu.) drugs. it has been found that the efficiency of (Tu) is higher than (At), especially at low concentrations of 100 ppm, whether by weight loss method or by Potentiometric method, and that it also proved the highest efficiency at high temperatures, which was also confirmed by the Arrhenius curves and the transition state. Potentiometric method also showed a higher stability of (Tu.) than (At.) by measuring the voltage within two hours, and the voltage also increased with the increase in the concentration of the expired drugs, and the current density decreased with the increase in concentration and increased with the increase in potential. As indicated by the Arrhenius curves, the transition state, the calculation of the activation energy, the change in enthalpy, and the change in entropy, the process of corrosion and inhibition are monitoring by the change in voltage using a voltage and current meter and by using Ag/AgCl as a reference electrode.

المراجع

[1] Al-Fahemi, J. H., Abdallah, M., Gad, E. A., & Jahdaly, B. A. A. L. (2016). Experimental and theoretical approach studies for melatonin drug as safely corrosion inhibitors for carbon steel using DFT. Journal of Molecular Liquids, 222, 1157-1163.

[2] Verma, C., Quraishi, M. A., & Rhee, K. Y. (2022). Natural ligands: Promising ecofriendly alternatives for corrosion protection and plethora of many prospects. Process Safety and

Environmental Protection, 162, 253-290.

[3] Rotaru, I., Varvara, S., Gaina, L., & Muresan, L. M. (2014). Antibacterial drugs as corrosion inhibitors for bronze surfaces in acidic solutions. Applied surface science, 321, 188-196.

[4] Golestani, G., Shahidi, M., & Ghazanfari, D. (2014). Electrochemical evaluation of antibacterial drugs as environment friendly inhibitors for corrosion of carbon steel in HCl solution. Applied surface science, 308, 347-362.

[5] Srivastava, M., Tiwari, P., Srivastava, S. K., Prakash, R., & Ji, G. (2017). Electrochemical investigation of Irbesartan drug molecules as an inhibitor of mild steel corrosion in 1 M HCl and 0.5 M H2SO4 solutions. Journal of Molecular Liquids, 236, 184-197.

[6] Abdallah, M., Zaafarany, I., Al-Karanee, S. O., & Abd El-Fattah, A. A. (2012). Antihypertensive drugs as an inhibitors for corrosion of aluminum and aluminium silicon alloys in aqueous

solutions. Arabian Journal of Chemistry, 5(2), 225-234.

[7] Vengatesh, G., Karthik, G., & Sundaravadivelu, M. (2017). A comprehensive study of ondansetron hydrochloride drug as a green corrosion inhibitor for mild steel in 1 M HCl medium. Egyptian journal of petroleum, 26(3), 705-719.

[8] Shukla, S. K., Singh, A. K., Ahamad, I., & Quraishi, M. A. (2009). Streptomycin: A commercially available drug as corrosion inhibitor for mild steel in hydrochloric acid solution. Materials Letters, 63(9-10), 819-822.

[9] Obot, I. B., Obi-Egbedi, N. O., & Umoren, S. A. (2009). Antifungal drugs as corrosion inhibitors for aluminium in 0.1 M HCl. Corrosion Science, 51(8), 1868-1875.

[10] Shukla, S. K., & Quraishi, M. A. (2010). Cefalexin drug: A new and efficient corrosion inhibitor for mild steel in hydrochloric acid solution. Materials Chemistry and Physics, 120(1), -147.

[11] Zadeh, A. S. K., Zandi, M. S., & Kazemipour, M. (2022). Corrosion protection of carbon steel in acidic media by expired bupropion drug; experimental and theoretical study. Journal of the Indian Chemical Society, 100522.

[12] Tajabadipour, H., Mohammadi-Manesh, H., & Shahidi-Zandi, M. (2022). Experimental and theoretical studies of carbon steel corrosion protection in phosphoric acid solution by expired

lansoprazole and rabeprazole drugs. Journal of the Indian Chemical Society, 99(1), 100285.

[13] Abdallah, M. (2004). Antibacterial drugs as corrosion inhibitors for corrosion of aluminium in hydrochloric solution. Corrosion Science, 46(8), 1981-1996.

[14] Singh, A. K., Pandey, A. K., Banerjee, P., Saha, S. K., Chugh, B., Thakur, S., ... & Singh, G. (2019). Eco-friendly disposal of expired anti-tuberculosis drug isoniazid

and its role in the protection of metal. Journal of Environmental Chemical Engineering, 7(2), 102971.

[15] Anadebe, V. C., Nnaji, P. C., Onukwuli, O. D., Okafor, N. A., Abeng, F. E., Chukwuike, V. I., ... & Barik, R. C. (2022). Multidimensional insight into the corrosion inhibition of salbutamol drug molecule on mild steel in oilfield acidizing fluid: Experimental and computer aided modelling approach. Journal of Molecular Liquids, 349, 118482.

[16] Mohamedien, H. A., Kamal, S. M., Taha, M., EL-Deeb, M. M., & El-Deen, A. G. (2022). Experimental and computational evaluations of cefotaxime sodium drug as an efficient and green corrosion inhibitor for aluminum in NaOH solution. Materials Chemistry and Physics, 290, 126546.

[17] Iroha, N. B., Anadebe, V. C., Maduelosi, N. J., Nnanna, L. A., Isaiah, L. C., Dagdag, O., ... & Ebenso, E. E. (2022). Linagliptin drug molecule as corrosion inhibitor for mild steel in 1 M HCl solution: Electrochemical, SEM/XPS, DFT and MC/MD simulation approach. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 130885.

[18] Tasić, Ž. Z., Mihajlović, M. B. P., Radovanović, M. B., Simonović, A. T., & Antonijević, M. M. (2021). Experimental and theoretical studies of paracetamol as a copper corrosion inhibitor. Journal of Molecular Liquids, 327, 114817.

[19] Merimi, C., Hammouti, B., Zaidi, K., Hafez, B., Elmsellem, H., & Kaya, S. (2022). Acetylsalicylic acid as an environmentally friendly corrosion inhibitor for carbon steel XC48 in

chloride environment. Journal of Molecular Structure, 134883.

[20] Sharma, S., Saha, S. K., Kang, N., Ganjoo, R., Thakur, A., Assad, H., & Kumar, A. (2022). Multidimensional analysis for corrosion inhibition by Isoxsuprine on mild steel in acidic

environment: Experimental and computational approach. Journal of Molecular Liquids, 357, 119129.

[21] Aslam, R., Mobin, M., Zehra, S., & Aslam, J. (2022). A comprehensive review of corrosion inhibitors employed to mitigate stainless steel corrosion in different environments. Journal of

Molecular Liquids, 119992.

[22] Barrodi, M. R., Mirzaee, A., Kafashan, A., Zahedifard, S., Majidi, H. J., Davoodi, A., & Hosseinpour, S. (2023). Synergistic effect in Tragacanth Gum-Ceftriaxone hybrid system as an environmentally friendly corrosion inhibitor for mild steel in acidic solutions. Materials Today Communications, 105390.

[23] Burhagohain, P., Sharma, G., & Bujarbaruah, P. M. (2022). Investigation of a few oxazolone molecules as corrosion inhibitor for API5LX60 steel in 1N H2SO4 solution. Egyptian Journal of

Petroleum, 31(3), 37-45.

[24] Saini, N., Kumar, R., Lgaz, H., Salghi, R., Chung, I. M., Kumar, S., & Lata, S. (2018). Minified dose of urispas drug as better corrosion constraint for soft steel in sulphuric acid solution. Journal of Molecular Liquids, 269, 371-380.

[25] Fernandes, F. D., Ferreira, L. M., & da Silva, M. L. C. P. (2021). Application of Psidium guajava L. leaf extract as a green corrosion inhibitor in biodiesel: biofilm formation and encrustation. Applied Surface Science Advances, 6, 100185.

[26] Almahdi, O., & Almassri, O. (2021). Corrosion Inhibition characteristics of Reinforced Steel in H2SO4 by benzoyl Thiourea. Journal of Pure & Applied Sciences, 20(2), 137-141.

[27] Suliman, M. S., Almadani, M. A., & Ahmied, E. K. (2019). The Inhibition of Mild Steel Corrosion by Sulphur Containing Organic Compound. Journal of Pure & Applied Sciences, 18(2).

[28] Matter A.B. Ayad, T. M. (2022). Study The Effect of Extract berry and mango leaves as a corrosion inhibitor of Cu, Carbon steel and Oil Pipelines. Journal of Pure & Applied Sciences, 21(1), 154-164.

[29] I. Elouali, B. Hammouti, A. Aouniti, Y. Ramli, M. Azougagh, E.M. Essassi, M. Bouachrine, Thermodynamic characterisation of steel corrosion in HCl in the presence of 2-phenylthieno (3, 2-b) quinoxaline, J. Mater. Environ. Sci. 1 (2010) 1.

[30] Biswas, B., Rogers, K., McLaughlin, F., Daniels, D., & Yadav, A. (2013). Antimicrobial activities of leaf extracts of guava (Psidium guajava L.) on two gramnegative and gram-positive

bacteria. International journal of microbiology, 2013.

[31] Verma, C., Quraishi, M. A., & Rhee, K. Y. (2021). Present and emerging trends in using pharmaceutically active compounds as aqueous phase corrosion inhibitors. Journal of Molecular

Liquids, 328, 115395.

[32] Lamaka, S., Souto, R. M., & Ferreira, M. G. (2010). In-situ visualization of local corrosion by Scanning Ion-selective Electrode Technique (SIET). Microscopy: Science, technology, applications and education, 3, 2162-2173.

التنزيلات

منشور

17/06/2025

كيفية الاقتباس

AB. Matter, H., M. Ayad, T., & A.I. Alkatly, A. (2023). The Corrosion Inhibition of The Carbon Steel and Oil Pipelines in 1 M H2SO4 by Expired Atarax and Tussinor, Drugs. مجلة العلوم الاساسية و التطبيقية - كلية العلوم - جامعة مصراتة ، ليبيا, (16), 93–101. https://doi.org/10.36602/jsba.2023.16.93

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